Comments on: Table of Functional Group Priorities for Nomenclature https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/ Wed, 19 Nov 2025 12:16:14 +0000 hourly 1 https://wordpress.org/?v=6.9.4 By: _Will https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-781191 Wed, 19 Nov 2025 12:16:14 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-781191 The written seems to be a fan Harry Potter….

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-777338 Wed, 22 Oct 2025 11:08:28 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-777338 In reply to Cesar Ordoñez.

It’s treated as a substituent to the parent chain and the parent chain has the suffix.

So diethyl ether for example has a longest chain of two. The naming becomes ethoxyethane.

methyl propyl ether would be methoxypropane

a more complex example would be 3-methoxypentane
or
1-bromo-2-methoxy-3,3 dimethyl hexane.

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By: Cesar Ordoñez https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-777337 Wed, 22 Oct 2025 11:00:31 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-777337 What happens with the ether group? Which priority it has? I know that the interfix for it is -oxy- but in which rank does it belong?

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By: eldwin cheung https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-702250 Tue, 06 Aug 2024 04:56:14 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-702250 i think there is a typo: 4-oxo-pentanoic acid should actually be 4-oxopentanoic acid.
hyphen before pentanoic acid should be removed

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By: alice kim https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-691739 Tue, 23 Apr 2024 16:06:50 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-691739 thanks, if there are cycloalkyl group, ethyl, and isopropyl group, which one takes the priority to get low number?

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By: Viraj K https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-686646 Tue, 05 Mar 2024 17:18:15 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-686646 What will the IUPAC name of this compound be?(— is triple bond, — is double bond and – is single bond)

CH—C-CH₂-CH₂-C–OH

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By: James Ashenhurst https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-649886 Fri, 10 Mar 2023 18:24:06 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-649886 In reply to Vaibhav.

Lowest locant. 3-hydroxynonan-4-one

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By: Vaibhav https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-649880 Fri, 10 Mar 2023 15:27:21 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-649880 I have a question.
Will lowest locant rule will be prefered or the order of preference of functional group will be preferred. I mean H3CCH2(OH)CHCOCH2CH2CH2CH2CH3.
will be named 3-hydroxynonan-4-one(locant rule followed)
Or 7-hydroxynonan-6-one (order of preference followed)

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By: Ammar https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-634873 Mon, 08 Aug 2022 19:03:44 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-634873 Example: 1-Bromo-3-Methoxypropane. Example*: 1-butoxy-5-chloropentane. Example: 1-Ethoxy-3-iodopropane. Example*: 1-Chloro-3-propoxypropane. Example: 1-Chloro-3-nitropropane Example*: 1-iodo-3-nitropropane *Examples does not contradict the ALPHABETICAL rule.]]> But if you look at the examples below ”Carefully” you will notice, numbering is as simple as we’re trying to make it.😂

Example: 1-Bromo-3-Methoxypropane.
Example*: 1-butoxy-5-chloropentane.

Example: 1-Ethoxy-3-iodopropane.
Example*: 1-Chloro-3-propoxypropane.

Example: 1-Chloro-3-nitropropane
Example*: 1-iodo-3-nitropropane

*Examples does not contradict the ALPHABETICAL rule.

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By: Ammar https://www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/#comment-634738 Sat, 06 Aug 2022 15:00:45 +0000 https://www.masterorganicchemistry.com/?p=1353#comment-634738 Example: 1-Bromo-3-Methoxypropane. Example*: 1-Chloro-5-butoxypentane. Example: 1-Ethoxy-3-iodopropane. Example*: 1-Chloro-3-butoxypropane. Example: 1-Chloro-3-nitropropane Example*: 3-iodo-1-nitropropane *Examples just contradict the ALPHABETICAL rule. I think it depends on the OXIDATION State of the Carbon. 'If a substituent Oxidises the Carbon more than other substituent on the same position, then numbering will start from that substituent which Oxidises more.'🙂]]> But if you look at the examples below ”Carefully” you will notice, numbering isn’t as simple as we’re trying to make it.😂

Example: 1-Bromo-3-Methoxypropane.
Example*: 1-Chloro-5-butoxypentane.

Example: 1-Ethoxy-3-iodopropane.
Example*: 1-Chloro-3-butoxypropane.

Example: 1-Chloro-3-nitropropane
Example*: 3-iodo-1-nitropropane

*Examples just contradict the ALPHABETICAL rule.

I think it depends on the OXIDATION State of the Carbon.
‘If a substituent Oxidises the Carbon more than other substituent on the same position, then numbering will start from that substituent which Oxidises more.’🙂

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